Experimental verification of line- and band-shape asymmetry in the Schumann–Runge system of O2
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Asymmetry sum rule for molecular predissociation
In the case of weak diatomic molecular predissociation by noninteracting, optically inactive continuum states, it is demonstrated that the predissociation line shape is more accurately represented by a Beutler-Fano profile than by a Lorentzian. The weak asymmetry that is found to occur is due principally to interactions with neighboring vibrational resonances. For this type of predissociation i...
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